Mysterious Molecules in Space
Tuesday, August 12, 2014
News Feature

Over the vast, empty reaches of interstellar space, countless small molecules tumble quietly though the cold vacuum. Forged in the fusion furnaces of ancient stars and ejected into space when those stars exploded, these lonely molecules account for a significant amount of all the carbon, hydrogen, silicon and other atoms in the universe. In fact, some 20 percent of all the carbon in the universe is thought to exist as some form of interstellar molecule.

Many astronomers hypothesize that these interstellar molecules are also responsible for an observed phenomenon on Earth known as the "diffuse interstellar bands," spectrographic proof that something out there in the universe is absorbing certain distinct colors of light from stars before it reaches the Earth. But since we don't know the exact chemical composition and atomic arrangements of these mysterious molecules, it remains unproven whether they are, in fact, responsible for the diffuse interstellar bands.

Now in a paper appearing in The Journal of Chemical Physics a group of scientists led by researchers at the Harvard-Smithsonian Center for Astrophysics in Cambridge, Mass. has offered a tantalizing new possibility: these mysterious molecules may be silicon-capped hydrocarbons like SiC3H, SiC4H and SiC5H, and they present data and theoretical arguments to back that hypothesis.

At the same time, the group cautions that history has shown that while many possibilities have been proposed as the source of diffuse interstellar bands, none has been proven definitively.

"There have been a number of explanations over the years, and they cover the gamut," says Michael McCarthy a senior physicist at the Harvard-Smithsonian Center for Astrophysics who led the study.